Electronic Theses and Dissertations

Date of Award

8-2018

Document Type

Dissertation

Degree Name

Ph.D. in Physics

Department

Physics and Astronomy

First Advisor

Cecille Labuda

Second Advisor

Joel Mobley

Third Advisor

Josh Gladden

Relational Format

Dissertation/thesis

Abstract

Wormlike micellar fluids, which flow when subjected to long-term stresses, are mechanically viscoelastic over shorter durations and can support shear waves. These fluids are birefringent under shear, allowing the study of shear wave propagation using both optical and acoustic modalities. Microstructural phase transitions of the micelles are temperature dependent and can manifest as sharp changes in the shear wave speed as a function of temperature. In this work, the behavior of shear waves in a fluid consisting of hexadecyltrimethylammonium bromide (CTAB) and sodium salicylate (NaSal) combined in a 5:3 ratio in a 200 mM concentration is studied. The temperature-dependent microstructural phase transitions were investigated in the temperature range of 4 – 40 °C. First, the temperature dependent behavior of mechanically generated shear waves was studied to identify these microstructural phase transitions and the implications of the shear wave speed variation over the temperature range were examined by measuring thermal properties. The thermal and spectral behavior of ultrasonically generated shear waves in the fluid was also studied by pulsing a HIFU (high intensity focused ultrasound) beam and generating a train of shear waves. The temperature and frequency dependent behavior was correlated with the rheological and microstructural properties of the WM fluid.

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