Honors Theses

Date of Award

Spring 4-22-2024

Document Type

Undergraduate Thesis

Department

Chemistry and Biochemistry

First Advisor

Ryan Fortenberry

Second Advisor

Gregory Tschumper

Third Advisor

Jason Ritchie

Relational Format

Dissertation/Thesis

Abstract

Computational chemistry focuses on finding solutions to the time-independent Schrödinger equation for systems of interest to study their molecular properties such as rovibrational spectral data. Any molecule containing more than one electron cannot be solved explicitly but coupled cluster theory offers one of the best approximations. One such application of this method is to molecules of astrochemical interest to support observation and experimental data. Chapters 2, 3, and 4 look at the performance of new couple cluster theory methods including composite and hybrid methods for ground and excited state rovibrational data. Chapters 5 - 9 use the previously mentioned methods to study a variety of molecules of astrochemical interest including inorganic oxides, MgC2, isomers of C5H2, and diaminomethane ((NH2)2CH2).

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