Honors Theses

Date of Award

Spring 5-8-2027

Document Type

Undergraduate Thesis

Department

Chemistry and Biochemistry

First Advisor

Courtney Roper

Second Advisor

James Stewart

Third Advisor

Brandon Nabors

Relational Format

Dissertation/Thesis

Abstract

Air pollution, especially fine particulate matter (PM₂.₅) and its components such as black carbon (BC), is a major environmental health concern due to its associations with respiratory disease, cardiovascular outcomes, and premature mortality. This study investigated BC concentrations and associated cancer and non-cancer health risks across selected urban and non-urban locations in Alabama.

PM₂.₅ filters were collected every three days from ten monitoring sites in Alabama between January and December 2014. BC concentrations were measured from collected filters using an optical transmissometer at 880 nm. Concentrations were calculated using light attenuation, filter area, sampling time, and flow rate. Health risk assessment was conducted using the U.S. Environmental Protection Agency human health risk assessment framework, including hazard identification, dose–response assessment, exposure assessment, and risk characterization. Chronic daily intake (CDI) was calculated for both children (ages 6–12) and adults (ages 21–70), followed by estimates of lifetime cancer risk (CR) and hazard quotient (HQ).

Results showed that average annual BC concentrations ranged from 2.28 to 3.18 μg/m³ across all sites, with no statistically significant differences observed between urban and non-urban locations. Cancer risk estimates exceeded the acceptable threshold of 1 × 10⁻⁴ at all sampling sites for both children and adults, indicating a potential carcinogenic risk associated with long-term BC exposure. In contrast, all HQ values remained below 1, suggesting that non-cancer adverse health effects are unlikely at the observed exposure levels. However, HQ values were consistently higher for children than adults across all locations.

The study concludes that BC exposure in Alabama presents a consistent cancer risk across both urban and non-urban environments, despite the absence of significant spatial differences in concentration. While non-cancer risks remain below regulatory concern thresholds, elevated cancer risk estimates highlight the need for continued monitoring and mitigation of BC emissions. These findings support the importance of targeted air quality management strategies and further research incorporating improved exposure assessment methods, such as personal monitoring, to better understand population-level health risk.

Creative Commons License

Creative Commons Attribution 4.0 International License
This work is licensed under a Creative Commons Attribution 4.0 International License.

Available for download on Wednesday, March 08, 2028

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