Electronic Theses and Dissertations

Date of Award

2019

Document Type

Thesis

Degree Name

M.S. in Chemistry

Department

Chemistry and Biochemistry

First Advisor

Jared H. Delcamp

Second Advisor

Amala Dass

Third Advisor

Jonah Jurss

Relational Format

dissertation/thesis

Abstract

The production of renewable fuels by the conversion of solar energy into chemical energy is a challenge. Photocatalytic and electrocatalytic conversion of CO2 to usable fuel precursors are approaches to overcoming this challenge. The two-electron reduction of carbon dioxide to carbon monoxide is an appealing process because CO can be used as a commodity chemical in industrial processes. Many molecular CO2 reduction catalysts have been reported and commonly use expensive late transition metals. These systems are inspired by natural photosynthesis and generally combine a photosensitizer, a catalyst, and a sacrificial electron donor. This work focuses nickel and gold complexes as catalysts for photocatalytic CO¬2 reduction.

Included in

Chemistry Commons

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